Experimental vibrational spectra of gas-phase tantalum cluster cations.
نویسندگان
چکیده
We present gas-phase infrared spectra of tantalum cluster cations containing 6-20 atoms. Infrared multiple photon dissociation of their complexes with argon atoms is used to obtain vibrational spectra in the region between 90 and 305 cm(-1). Many spectra have features in common with the vibrational spectra of the lighter homologs, vanadium and niobium, pointing to a common cluster growth mechanism.
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ورودعنوان ژورنال:
- The Journal of chemical physics
دوره 127 23 شماره
صفحات -
تاریخ انتشار 2007